Oyster Shells or Shells in General comprise CACO3 ie Calcium Carbonate ...
This is a very poorly soluble species therefore
Quantities as Tom stipulated are required to afford any manner of buffering capacity contribution with regard the general acidification respiration Processes occurring continuously in ponds with subsequent PH declines over time ..
It will however still "Buffer" at PH Values above the neutral 7 albeit to a much lesser degree

not forgetting also that unlike Bicarb (baking soda) CC will add considerably to both the GH and TDS
With varying pH
We now consider the problem of the maximum solubility of calcium carbonate in normal atmospheric conditions (\scriptstyle P_{\mathrm{CO}_2} = 3.5 × 10−4 atm) when the pH of the solution is adjusted. This is for example the case in a swimming pool where the pH is maintained between 7 and 8 (by addition of sodium bisulfate NaHSO4 to decrease the pH or of sodium bicarbonate NaHCO3 to increase it). From the above equations for the solubility product, the hydration reaction and the two acid reactions, the following expression for the maximum [Ca2+] can be easily deduced:
[\text{Ca}^{2+}]_\text{max} = \frac{K_\text{sp}} {K_\text{h}K_\text{a1}K_\text{a2}k_\text{H}} \frac{[\text{H}^+]^2}{P_{\text{CO}_2}}
showing a quadratic dependence in [H+]. The numerical application with the above values of the constants gives[citation needed]
pH 7.0 7.2 7.4 7.6 7.8 8.0 8.2 8.27 8.4
[Ca2+]max (10−6mol/L) 180 71.7 28.5 11.4 4.52 1.80 0.717 0.519 0.285
[Ca2+]max (mg/L) 7.21 2.87 1.14 0.455 0.181 0.0721 0.0287 0.0208 0.0114
* decreasing the pH from 8 to 7 increases the maximum Ca2+ concentration by a factor 100. Water with a pH maintained to 7 can dissolve up to 15.9 g/L of CaCO3. This explains the high Ca2+ concentration in some mineral waters with pH close to 7.
* note that the Ca2+ concentration of the previous table is recovered for pH = 8.27
* keeping the pH to 7.4 in a swimming pool (which gives optimum HClO/ClO− ratio in the case of "chlorine" maintenance) results in a maximum Ca2+ concentration of 1010 mg/L. This means that successive cycles of water evaporation and partial renewing may result in a very hard water before CaCO3 precipitatesBeing a huge Fan of Experimentation

I ran a small 8 day exercise in this regard and the results are as follows ..
Starting PH was 7.2 KH was 40ppm and GH 62 ppm .. No respiration activity ie life forms were initially in situ this being "Tap Water" without chlorine ..
I didn`t have time to measure values daily but by day 2 the PH was 7.36 and steadily increased throughout as did the other values measured ...
Allowing for Evaporation concentration of both GH KH values increases .. Buffering did still occur ...
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these will take a second Post which I`ll try to upload later

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